Polymeric arrangements of P-Se anions and a first insight into their reactivity

Weifeng Shi, Maryam Shafaei-Fallah, Christopher E. Anson, Alexander Rothenberger*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

The reactions of the P/Se-precursor Woollins' reagent [PhP(Se)-Se] 2 with alkali-metal salts offer new perspectives for the synthesis of metal aggregates containing P-Se anions. Depending on the alkali-metal thiolates polymeric arrangements of [PhPSe3]2- or [PhPSe2Se-SeSe2PPh]2- dianions are observed and the mechanisms of their formation described.

Original languageEnglish (US)
Pages (from-to)2979-2983
Number of pages5
JournalDalton Transactions
Issue number24
DOIs
StatePublished - 2006
Externally publishedYes

ASJC Scopus subject areas

  • Inorganic Chemistry

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