Poly[(μ3-hydrogenphosphato)(4H-1,2,4-triazole-κN 1)zinc]

Hafid Aitenneite*, Abdeslam El Bouari, Said Sebti, Mohamed Saadi, Lahcen El Ammari, Karim Adil

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The asymmetric unit of the title compound, [Zn(HPO4)(C 2H3N3)] n , contains one Zn2+ cation, one (HPO4)2- anion and a 1,2,4 triazole ligand. The Zn2+ cation is coordinated in a quite regular tetrahedral geometry by O atoms from three phosphate groups and a tertiary N atom from the triazole ring. Each phosphate anion is connected to three ZnII cations, leading to a series of corrugated organic-inorganic layers parallel to the ac plane. The overall structure involves stacking of complex hybrid organic-inorganic layers along the b axis. Cohesion in the crystal is ensured by an infinite three-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds between the phosphate groups and the triazole ligands.

Original languageEnglish (US)
Pages (from-to)m1426-m1427
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number11
DOIs
StatePublished - Nov 1 2012

Keywords

  • R factor = 0.021
  • T = 296 K
  • data-to-parameter ratio = 33.2
  • mean ̄(N-C) = 0.002 Å
  • single-crystal X-ray study
  • wR factor = 0.051

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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