Phosphine-stabilized copper-antimony clusters: Syntheses, structures, and theoretical investigations of [Cu12(SbSiMe3) 6(PiPr3)6], [Cu40Sb 12(PMe3)20], and [Cu45Sb 16(PEt2Me)16]

Reinhart Ahlrichs*, Dieter Fenske, Mary McPartlin, Alexander Rothenberger, Claudia Schrodt, Stephan Wieber

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Molecular alloys: The composition and properties of the title compounds suggests that they can be regarded as molecular alloys. The single-crystal structures of these phosphine-stabilized compounds are determined (see picture for structure of [Cu45Sb16(PEt2Me) 16]; Sb red, Cu blue, P green) and confirmed by density functional theory (DFT) calculations. (Figure Presented)

Original languageEnglish (US)
Pages (from-to)3932-3936
Number of pages5
JournalAngewandte Chemie - International Edition
Volume44
Issue number25
DOIs
StatePublished - Jun 20 2005

Keywords

  • Antimony
  • Cluster compounds
  • Copper
  • Density functional calculations
  • Molecular alloys

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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