Oxidation of a one-dimensional coordination polymer and synthesis of the macrocyclic silver complex [Ag12(PhS2P-PS 2Ph)6(dppeS)6]

Dieter Fenske, Alexander Rothenberger, Maryam Shafaei Fallah

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20 Scopus citations

Abstract

The cluster chemistry with functionalised trimethylsilyl re-agents was investigated. The oxidation of the one-dimensional coordination polymer 1/ [{Ag2(PhS2P-PS2Ph)-dppe} ·dppe] leads to the formation of [Ag 12(PhS2-P-PS2Ph)6(dppeS) 6] (dppeS = Ph2P(CH2)2P(S)Ph 2]. The dianionic ligand [PhPS2-PS2Ph] 2- could possibly give rise to a new class of macrocyclic transition-metal chalcogenides.

Original languageEnglish (US)
Pages (from-to)59-62
Number of pages4
JournalEuropean Journal of Inorganic Chemistry
Issue number1
DOIs
StatePublished - Jan 7 2005

Keywords

  • Calcogenides
  • Macrocycle
  • P ligands
  • S ligands
  • Silver

ASJC Scopus subject areas

  • Inorganic Chemistry

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