Ormosil-nafion composite membranes for PEM fuel cells

B. Mecheri, A. D'Epifanio, E. Traversa, S. Licoccia*

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

Composite Nafion-based membranes were prepared and characterized, using an organosilane derivative (sulfonated diphenylsilanediol, SDPSD) as a filler. The formation of the composite substantially modified the properties of the Nafion matrix in terms of proton conductivity and thermal stability. The structural and electrochemical performance of the membranes were investigated by means of electrochemical impedance spectroscopy, differential scanning calorimetry (DSC), field emission scanning electron microscopy (FE-SEM) and water uptake measurements. Both conductivity values and thermal features of the composite Nafion/SDPSD demonstrated that it has satisfactory proton conductivity values up to 160°C, and it is then suitable for application as an electrolyte in polymer electrolyte fuel cells operating at intermediate temperature. copyright The Electrochemical Society.

Original languageEnglish (US)
Title of host publicationNanostructured Metal Oxides
Subtitle of host publicationProcessing and Applications
Pages157-162
Number of pages6
Volume3
Edition9
DOIs
StatePublished - 2006
Externally publishedYes
EventNanostructured Metal Oxides: Processing and Applications - 210th Electrochemical Society Meeting - Cancun, Mexico
Duration: Oct 29 2006Nov 3 2006

Other

OtherNanostructured Metal Oxides: Processing and Applications - 210th Electrochemical Society Meeting
CountryMexico
CityCancun
Period10/29/0611/3/06

ASJC Scopus subject areas

  • Engineering(all)

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