Accurate air quality monitoring requires processing of multi-dimensional, multi-location sensor data, which has previously been considered in centralised machine learning models. These are often unsuitable for resource-constrained edge devices. In this article, we address this challenge by: (1) designing a novel hybrid deep learning model for hourly PM2.5 pollutant prediction; (2) optimising the obtained model for edge devices; and (3) examining model performance running on the edge devices in terms of both accuracy and latency. The hybrid deep learning model in this work comprises a 1D Convolutional Neural Network (CNN) and a Long Short-Term Memory (LSTM) to predict hourly PM2.5 concentration. The results show that our proposed model outperforms other deep learning models, evaluated by calculating RMSE and MAE errors. The proposed model was optimised for edge devices, the Raspberry Pi 3 Model B+ (RPi3B+) and Raspberry Pi 4 Model B (RPi4B). This optimised model reduced file size to a quarter of the original, with further size reduction achieved by implementing different post-training quantisation. In total, 8272 hourly samples were continuously fed to the edge device, with the RPi4B executing the model twice as fast as the RPi3B+ in all quantisation modes. Full-integer quantisation produced the lowest execution time, with latencies of 2.19 s and 4.73 s for RPi4B and RPi3B+, respectively.