Novel quasi-symmetric solid oxide fuel cells with enhanced electrochemical performance

Yonghong Chen, Zhuanxia Cheng, Yang Yang, Qingwen Gu, Dong Tian, Xiaoyong Lu, Weili Yu, Lin Bin

Research output: Contribution to journalArticlepeer-review

30 Scopus citations

Abstract

Symmetrical solid oxide fuel cell (SSOFC) using same materials as both anode and cathode simultaneously has gained extensively attentions, which can simplify fabrication process, minimize inter-diffusion between components, enhance sulfur and coking tolerance by operating the anode as the cathode in turn. With keeping the SSOFC's advantages, a novel quasi-symmetrical solid oxide fuel cell (Q-SSOFC) is proposed to further improve the performance, which optimally combines two different SSOFC electrode materials as both anode and cathode simultaneously. PrBaFe2O5+δ (PBFO) and PrBaFe1.6Ni0.4O5+δ (PBFNO, Fe is partially substituted by Ni.) are prepared and applied as both cathode and anode for SSOFC, which exhibit desirable chemical and thermal compatibility with Sm0.8Ce0.2O1.9 (SDC) electrolyte. PBFO cathode exhibits higher oxygen reduction reaction (ORR) activity than PBFNO cathode in air, whereas PBFNO anode exhibits higher hydrogen oxidation reaction (HOR) activity than PBFO anode in H2. The as-designed Q-SSOFC of PBFNO/SDC/PBFO exhibits higher electrochemical performance than the conventional SSOFCs of both PBFO/SDC/PBFO and PBFNO/SDC/PBFNO. The superior performance of Q-SSOFC is attributed to the lowest polarization resistance (Rp). The newly developed Q-SSOFCs open doors for further improvement of electrochemical performance in SSOFC, which hold more promise for various potential applications. © 2016 Elsevier B.V. All rights reserved.
Original languageEnglish (US)
Pages (from-to)109-117
Number of pages9
JournalJournal of Power Sources
Volume310
DOIs
StatePublished - Feb 16 2016

Fingerprint Dive into the research topics of 'Novel quasi-symmetric solid oxide fuel cells with enhanced electrochemical performance'. Together they form a unique fingerprint.

Cite this