NMR study of localization and mobility of 1-phenylethanol enantiomers in homochiral metal-organic sorbent Zn2(bdc)(S-lac)(dmf)

M. R. Gallyamov, Maxim Yutkin, N. K. Moroz, S. G. Kozlova*, S. P. Gabuda

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Structural features of localization of chiral isomers of 1-phenylethanol (R-PhEtOH and S-PhEtOH) and their mobility activation in homochiral metal-organic [Zn2(bdc)(S-lac)(dmf)] sorbent were studied with 1H and 13C NMR methods. 13C NMR chemical shifts do not show obvious advantage of selective interaction of molecule guests. But activation molecular mobility of S-PhEtOH and R-PhEtOH clearly indicates that stabilization of [Zn2(bdc)(S-lac)(dmf)]·S-PhEtOH structure is more preferable than stabilization of [Zn2(bdc)(S-lac)(dmf)]·R-PhEtOH structure.

Original languageEnglish (US)
Pages (from-to)578-581
Number of pages4
JournalMagnetic Resonance in Chemistry
Volume53
Issue number8
DOIs
StatePublished - Aug 1 2015

Keywords

  • 1-phenylethanol enantiomers
  • H and C NMR
  • homochiral metal-organic sorbent

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)

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