Nitrogen atom transfer mediated by a new PN3P-pincer nickel core: Via a putative nitrido nickel intermediate

Changguang Yao, Xiufang Wang, Kuo-Wei Huang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

A 2nd generation PN3P-pincer azido nickel complex (PN3P)Ni(N3) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN3P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.

Original languageEnglish (US)
Pages (from-to)3940-3943
Number of pages4
JournalChemical Communications
Volume54
Issue number32
DOIs
StatePublished - Jan 1 2018

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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