Nickel-Catalyzed Synthesis of Silanes from Silyl Ketones

Watchara Srimontree, Waranya Lakornwong, Magnus Rueping

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

An unprecedented nickel-catalyzed decarbonylative silylation via CO extrusion intramolecular recombination fragment coupling of unstrained and nondirecting group-Assisted silyl ketones is described. The inexpensive and readily available catalyst performs under mild reaction conditions and enables the synthesis of structurally diverse arylsilanes, including heterocyclic and natural product derivatives.
Original languageEnglish (US)
Pages (from-to)9330-9333
Number of pages4
JournalOrganic Letters
Volume21
Issue number23
DOIs
StatePublished - Nov 8 2019

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