Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway

Magnus Rueping, Shao-Chi Lee, Lin Guo, Huifeng Yue, Hsuan-Hung Liao

Research output: Contribution to journalArticlepeer-review

40 Scopus citations

Abstract

A nickel-catalyzed decarbonylative silylation, borylation, and amination of amides has been developed. This new methodology allows the direct interconversion of amides to arylsilanes, arylboronates, and arylamines and enables a facile route for carbon–heteroatom bond formations in a straightforward and mild fashion.
Original languageEnglish (US)
Pages (from-to)2594-2598
Number of pages5
JournalSynlett
Volume28
Issue number19
DOIs
StatePublished - Oct 23 2017

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