New optically active organotin compounds for heterogeneous bimetallic catalysis

Christine Lucas, Catherine C. Santini, Martina Prinz, Marie Anne Cordonnier, Jean-Marie Maurice Basset, Marie Françoise Connil, Bernard Jousseaume*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

Chiral tin(IV) derivatives with two or three chiral centers adjacent to the metal (-)-Ment2SnMe2, (-)-Ment2SnPh2, (-)-Ment3SnCl, (-)-Ment3SnH; (-)-Ment = (1R,2S,5R)-1-chloro-5-methyl-2-isopropylcyclohexane, R2Sn[CH(Me)(n-Hex)]2 (R = Bu or Ph) have been prepared either by the coupling of menthylmagnesium chloride with tin halides or by the reaction of lithium stannates with optically active (2-octyl)tosylate. The stereospecificity of both processes was remarkably high, leading to new optically pure organotin reagents which have been fully characterized.

Original languageEnglish (US)
Pages (from-to)101-106
Number of pages6
JournalJournal of Organometallic Chemistry
Volume520
Issue number1-2
DOIs
StatePublished - Aug 9 1996

Keywords

  • Heterogeneous bimetallic catalysis
  • Lithium stannate
  • Optically active organotin compounds
  • Tin

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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