New optically active organogermane compounds containing the adamantyl radical for heterogeneous bimetallic catalysis. Part II

Mostafa Taoufik*, Catherine C. Santini, Jean-Marie Maurice Basset

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Chiral organogermane(IV) derivatives H3GeAdCH2CO2(-)-menthyl, H3GeAdCH2CH2O(-)-bornyl and H3GeAdCH2CH2O2CCH 2O(-)-menthyl (Ad=adamantyl) have been prepared in six steps from the 1-bromoadamantane. The new optically pure organogermane reagents which have been fully characterised have been used in the preparation of heterogeneous bimetallic catalysts.

Original languageEnglish (US)
Pages (from-to)128-136
Number of pages9
JournalJournal of Organometallic Chemistry
Volume580
Issue number1
DOIs
StatePublished - May 15 1999

Keywords

  • Germanium
  • Heterogeneous bimetallic catalysts
  • Optically active organogermane compounds

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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