New approach for understanding the mechanism of butadiene and butenol reactions with Pd(TPPTS) 3 catalyst in water

Emile Kuntz*, Jean-Marie Maurice Basset, Denis Bouchu, Gregory Godard, Frédéric Lefebvre, Nicolas Legagneux, Christine Lucas, Daniel Michelet

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

The complex Pd(TPPTS) 3 reacts in water at room temperature with butenols (ionization) or butadiene (protonation) to produce two isomeric hydrosoluble η 3-allylic palladium complexes ([Pd(syn-C 4)(TPPTS) 2] + and [Pd(anti-C 4)(TPPTS) 2] +) and three isomers of butenylphosphonium salts of TPPTS. The pH has a great influence on the reaction rates and on the stability of the products.

Original languageEnglish (US)
Pages (from-to)523-526
Number of pages4
JournalOrganometallics
Volume29
Issue number3
DOIs
StatePublished - Feb 8 2010

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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