N-annulated perylene fused porphyrins with enhanced near-IR absorption and emission

Chongjun Jiao, Kuo-Wei Huang, Zhenping Guan, Qinghua Xu, Jishan Wu

Research output: Contribution to journalArticlepeer-review

81 Scopus citations

Abstract

N-Annulated perylene fused porphyrins 1 and 2 were synthesized by oxidative dehydrogenation using a Sc(OTf)3/DDQ system. These newly synthesized hybrid molecules are highly soluble in organic solvents and exhibit remarkably intense near-IR absorption, as well as detectable photoluminescence quantum yields, all of which are comparable to or even exceed those of either meso-β doubly linked porphyrin dimer/trimer or bis/tri-N-annulated rylenes. © 2010 American Chemical Society.
Original languageEnglish (US)
Pages (from-to)4046-4049
Number of pages4
JournalOrganic Letters
Volume12
Issue number18
DOIs
StatePublished - Sep 17 2010

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry

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