N -annulated perylene as an efficient electron donor for porphyrin-based dyes: Enhanced light-harvesting ability and high-efficiency Co(II/III)-based dye-sensitized solar cells

Jie Luo, Mingfei Xu, Renzhi Li, Kuo-Wei Huang, Changyun Jiang, Qingbiao Qi, Wangdong Zeng, Jie Zhang, Chunyan Chi, Peng Wang, Jishan Wu

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248 Scopus citations

Abstract

Porphyrin-based dyes recently have become good candidates for dye-sensitized solar cells (DSCs). However, the bottleneck is how to further improve their light-harvesting ability. In this work, N-annulated perylene (NP) was used to functionalize the Zn-porphyrin, and four "push-pull"-type NP-substituted and fused porphyrin dyes with intense absorption in the visible and even in the near-infrared (NIR) region were synthesized. Co(II/III)-based DSC device characterizations revealed that dyes WW-5 and WW-6, in which an ethynylene spacer is incorporated between the NP and porphyrin core, showed pantochromatic photon-to-current conversion efficiency action spectra in the visible and NIR region, with a further red-shift of about 90 and 60 nm, respectively, compared to the benchmark molecule YD2-o-C8. As a result, the short-circuit current density was largely increased, and the devices displayed power conversion efficiencies as high as 10.3% and 10.5%, respectively, which is comparable to that of the YD2-o-C8 cell (η = 10.5%) under the same conditions. On the other hand, the dye WW-3 in which the NP unit is directly attached to the porphyrin core showed a moderate power conversion efficiency (η = 5.6%) due to the inefficient π-conjugation, and the NP-fused dye WW-4 exhibited even poorer performance due to its low-lying LUMO energy level and nondisjointed HOMO/LUMO profile. Our detailed physical measurements (optical and electrochemical), density functional theory calculations, and photovoltaic characterizations disclosed that the energy level alignment, the molecular orbital profile, and dye aggregation all played very important roles on the interface electron transfer and charge recombination kinetics. © 2013 American Chemical Society.
Original languageEnglish (US)
Pages (from-to)265-272
Number of pages8
JournalJournal of the American Chemical Society
Volume136
Issue number1
DOIs
StatePublished - Dec 24 2013

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: J.W. acknowledges financial support from the IMRE Core Funding (IMRE/13-1C0205) and MOE Tier 2 grant (MOE2011-T2-2-130). P.W. thanks the National 973 Program (No. 2011CBA00702) and the National Science Foundation of China (No. 51203150). K.-W.H. acknowledges financial support from KAUST.

ASJC Scopus subject areas

  • Biochemistry
  • Colloid and Surface Chemistry
  • Chemistry(all)
  • Catalysis

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