Molecular insight into surface organometallic chemistry through the combined use of 2D HETCOR solid-state NMR spectroscopy and silsesquioxane analogues

Mathieu Chabanas, Elsje Alessandra Quadrelli, Bernard Fenet, Christophe Copéret, Jean Thivolle-Cazat, Jean Marie Basset, Anne Lesage, Lyndon Emsley

Research output: Contribution to journalArticlepeer-review

71 Scopus citations

Abstract

Feher cage analogues, such as 1, provide easy access to models of surface structures such as 2, and give a better understanding of surface reactions. In addition, surface complexes such as 2 can be fully characterized by high-resolution 1D and 2D solid-state NMR spectroscopy.

Original languageEnglish (US)
Pages (from-to)4493-4496
Number of pages4
JournalAngewandte Chemie - International Edition
Volume40
Issue number23
DOIs
StatePublished - Dec 3 2001

Keywords

  • NMR spectroscopy
  • Organometallic chemistry
  • Silicates
  • Surface chemistry
  • Tantalum

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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