MOF-Derived Isolated Fe Atoms Implanted in N-Doped 3D Hierarchical Carbon as an Efficient ORR Electrocatalyst in Both Alkaline and Acidic Media

Xiaodong Chen, Ning Wang, Kui Shen, Yangkai Xie, Yongpeng Tan, Yingwei Li

Research output: Contribution to journalArticlepeer-review

42 Scopus citations

Abstract

In order to improve the catalytic performance of oxygen reduction reaction (ORR), it is pivotal to increase the density and accessibility of the active sites. Herein, we have developed a template-free melamine-assisted cocalcined strategy to afford Fe-embedded and N-doped carbons (Fe-N-C) with not only high density of atomically dispersed Fe-Nx active sites but also abundant three-dimensional interconnected mesopores by directly pyrolyzing Fe-ZIF-8 covered with a controllable melamine layer. It is demonstrated that the introduction of melamine in the precursor plays a key role in constructing various carbonized products with controllable morphology, porosity, and components. With an optimal mass ratio 1:1 of melamine to Fe-ZIF-8, the resultant Fe@MNC-1 exhibits excellent ORR activity and stability, which exceeds 20 wt % commercial Pt/C catalyst (with a half-wave potential of 0.88 V vs 0.85 V) in an alkaline electrolyte and is even comparable to the commercial Pt/C catalyst (with a half-wave potential of 0.78 V vs 0.80 V) in an acidic electrolyte. To the best of our knowledge, Fe@MNC-1 can be ranked among the best nonprecious metal electrocatalysts for ORR in both alkaline and acidic media. The present synthetic strategy may provide a new opportunity for the design and construction of metal-organic framework-derived nanomaterials with rational composition and a desired porous structure to boost their electrocatalytic performance.
Original languageEnglish (US)
Pages (from-to)25976-25985
Number of pages10
JournalACS Applied Materials and Interfaces
Volume11
Issue number29
DOIs
StatePublished - Jun 27 2019

Bibliographical note

KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work was supported by the National Natural Science Foundation of China (21825802, 21436005, 21576095, 21606087), Guangdong Natural Science Funds for Distinguished Young Scholar (2018B030306050), the Science and Technology Program of Guangzhou (201804020009), the Pearl River S&T Nova Program of Guangzhou (201806010140), the State Key Laboratory of Pulp and Paper Engineering (2017ZD04, 2018TS03), and the Natural Science Foundation of Guangdong Province (2016A050502004, 2017A030312005).

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