Modulating the packing of [Cu24(isophthalate)24] cuboctahedra in a triazole-containing metal–organic polyhedral framework

Yong Yan, Mikhail Suetin, Elena Bichoutskaia, Alexander J. Blake, David R. Allan, Sarah A. Barnett, Martin Schröder*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

107 Scopus citations

Abstract

The highly porous (3,24)-connected framework NOTT-122 incorporates a C3-symmetric angularly connected isophthalate linker containing 1,2,3-triazole rings and shows body-centered tetragonal packing of [Cu24(isophthalate)24] cuboctahedra. This unique packing, coupled with the high density of free N-donor sites, is responsible for the simultaneous high H2, CH4 and CO2 adsorption capacities in desolvated NOTT-122a.

Original languageEnglish (US)
Pages (from-to)1731-1736
Number of pages6
JournalChemical Science
Volume4
Issue number4
DOIs
StatePublished - Mar 4 2013

ASJC Scopus subject areas

  • Chemistry(all)

Fingerprint

Dive into the research topics of 'Modulating the packing of [Cu<sub>24</sub>(isophthalate)<sub>24</sub>] cuboctahedra in a triazole-containing metal–organic polyhedral framework'. Together they form a unique fingerprint.

Cite this