Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis

Justyna Czaban-Jozwiak, Lukasz Wozniak, Artur Ulikowski, Katarzyna Kwiecinska, Adam A. Rajkiewicz, Karol Grela

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro-activated Ru catalyst is optimal for this transformation. The reported transformation was used to prepare selected hybrid steroid-POSS compounds.
Original languageEnglish (US)
Pages (from-to)1722
JournalMolecules
Volume23
Issue number7
DOIs
StatePublished - Jul 11 2018
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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