Metathesis of phosphorus-containing olefins catalysed by a cyclometallated aryloxo(chloro)neopentylidene-tungsten complex

Michel Leconte, Isabella Jourdan, Salvatore Pagano, Frédéric Lefebvre, Jean-Marie Maurice Basset*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

37 Scopus citations

Abstract

A cyclometallated O,O′-diphenyl aryloxy(chloro)neopentylidene- tungsten complex W(OAr)(OAr)(CHCMe3)Cl(OEt2) 1 is able to carry out metathesis of phosphorous containing olefins; diallylphenyl phosphane is metathetized intramolecularly to give the corresponding phospholene derivative 2 and allyldiphenyl phosphane gives the corresponding bisphosphane 3.

Original languageEnglish (US)
Pages (from-to)857-858
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number8
DOIs
StatePublished - Dec 1 1995

ASJC Scopus subject areas

  • Molecular Medicine

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