Metathesis of Ω-unsaturated glycosides with chloro-aryloxide complexes of tungsten, as a new synthetic route leading to unsaturated neutral bolaforms

Jan Ramza*, Gerard Descotes, Jean Marie Basset, Andy Mutch

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

Glucosides of unsaturated alcohols, bearing different functional groups on the carbohydrate units, underwent catalytic metathesis reaction affording neutral bolaforms in good yields. Tungsten aryloxo-complexes (1 and 2), due to large steric hindrance, were found to be superior catalysts for this process.

Original languageEnglish (US)
Pages (from-to)125-136
Number of pages12
JournalJournal of Carbohydrate Chemistry
Volume15
Issue number2
StatePublished - 1996
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

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