Metal-free Bronsted acid catalyzed transfer hydrogenation: enantioselective synthesis of tetrahydroquinolines.

Magnus Rueping, Thomas Theissmann, Andrey P Antonchick

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

Diphenylphosphate catalyzes the metal-free redn. of ketimines under hydrogen-transfer conditions with Hantzsch dihydropyridine as the hydrogen source. The asym. variant of this procedure using 1 mol % of a chiral BINOL-phosphate I as catalyst is reported. [on SciFinder(R)]
Original languageEnglish (US)
Title of host publicationMetal-free Bronsted acid catalyzed transfer hydrogenation: enantioselective synthesis of tetrahydroquinolines.
Number of pages7
StatePublished - 2007
Externally publishedYes

Keywords

  • chiral BINOL phosphate catalyst Hantzsch dihydropy
  • diphenylphosphate catalyst Hantzsch dihydropyridin
  • tetrahydroquinoline stereoselective prepn

Fingerprint Dive into the research topics of 'Metal-free Bronsted acid catalyzed transfer hydrogenation: enantioselective synthesis of tetrahydroquinolines.'. Together they form a unique fingerprint.

Cite this