Mesomeric Effect of Substituents in Stereoregular Polyenes

M. B. Zuev, S. E. Nefed'ev, A. N. Ustyugov, B. M. Zuev, G. B. Kamardin, N. V. Ivanova, Jean-Luc Bredas

Research output: Contribution to journalArticlepeer-review

Abstract

A formal model of mesomeric effect in stereoregular polyenes has been developed on the basis of quantum-chemical structural data, and mesomeric constants for a series of π-electron-donor and π-electron-acceptor groups have been calculated. The proposed substituent scale can be used to design molecular structures with a high first hyperpolarizability, which are necessary for development of organic materials for nonlinear optics.

Original languageEnglish (US)
Pages (from-to)1844-1849
Number of pages6
JournalRussian Journal of General Chemistry
Volume68
Issue number11
StatePublished - Nov 1 1998

ASJC Scopus subject areas

  • Chemistry(all)

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