Hydrogen peroxide (H2O2) is formed during hydrocarbon combustion and controls the system reactivity under intermediate temperature conditions. Here, we measured the rate of hydrogen peroxide decomposition behind reflected shock waves using midinfrared absorption of H2O 2 near 7.7 μm. We performed the experiments in diluted H 2O2/Ar mixtures between 930 and 1235 K and at three different pressures (1, 2, and 10 atm). Under these conditions, the decay of hydrogen peroxide is sensitive only to the decomposition reaction rate, H 2O2 + M → 2OH + M (k1). The second-order rate coefficient at low pressures (1 and 2 atm) did not exhibit any pressure dependence, suggesting that the reaction was in the low-pressure limit. The rate data measured at 10 atm exhibited falloff behavior. The measured decomposition rates can be expressed in Arrhenius forms as follows: k1(1 and 2 atm)=10(16.29±0.12)× exp (-21993±301/T)(cm 3 mol -1s-1) k1(10 atm)=10(15.24±0.10)× exp (-19955±247/T)(cm 3 mol -1s-1) © 2013 Wiley Periodicals, Inc.
Bibliographical noteKAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We would like to acknowledge the funding provided by the Clean Combustion Research Center at King Abdullah University of Science and Technology, Thuwal, Saudi Arabia, and by Saudi Aramco under the FUELCOM program. Dr. Fittschen thanks the European Commission for funding through the Erasmus Mundus Gulf Countries Programme (EMA2-STRAND 2, LOT4).
ASJC Scopus subject areas
- Organic Chemistry
- Physical and Theoretical Chemistry
- Inorganic Chemistry