Mathematical modeling and simulation of nanopore blocking by precipitation

M-T Wolfram, M Burger, Z S Siwy

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

High surface charges of polymer pore walls and applied electric fields can lead to the formation and subsequent dissolution of precipitates in nanopores. These precipitates block the pore, leading to current fluctuations. We present an extended Poisson-Nernst-Planck system which includes chemical reactions of precipitation and dissolution. We discuss the mathematical modeling and present 2D numerical simulations. © 2010 IOP Publishing Ltd.
Original languageEnglish (US)
Pages (from-to)454101
JournalJournal of Physics: Condensed Matter
Volume22
Issue number45
DOIs
StatePublished - Oct 29 2010
Externally publishedYes

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