Maghemite polymer nanocomposites with modulated magnetic properties

A. Millan*, F. Palacio, Andrea Falqui, E. Snoeck, V. Serin, A. Bhattacharjee, V. Ksenofontov, P. Gütlich, I. Gilbert

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

49 Scopus citations

Abstract

A method is presented for the production of maghemite polymer nanocomposites with modulated magnetic properties. Magnetic nanocomposites prepared using this method show regular variation in the magnetic blocking temperature from 2 K to 300 K, and variation in the saturation magnetization from 0 to 50 emu g-1 (Fe2O3). The method is based on the in situ formation of maghemite nanoparticles in nitrogen-base polymer matrixes. The particle size can be varied regularly from 1.5 nm to 16 nm by changing the ratio of iron loading in the polymer and/or the Fe(II)/Fe(III) ratios. The particles are isolated and uniformly distributed within the matrix. The materials were characterized by electron microscopy, electron energy loss spectroscopy, Mössbauer spectroscopy, infrared spectroscopy, small angle X-ray scattering, wide angle X-ray scattering and magnetic measurements. The nanocomposites obtained are useful model material for the study of the magnetic behavior of magnetic nanoparticles, as well as for use in many industrial and biomedical applications.

Original languageEnglish (US)
Pages (from-to)2201-2209
Number of pages9
JournalActa Materialia
Volume55
Issue number6
DOIs
StatePublished - Apr 1 2007

Keywords

  • Maghemite
  • Magnetic properties
  • Nanocomposite
  • Nanoparticles

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Polymers and Plastics
  • Metals and Alloys

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