Low-Temperature Processed Ga-Doped ZnO Coatings from Colloidal Inks

Enrico Della Gaspera, Marco Bersani, Michela Cittadini, Massimo Guglielmi, Diego Pagani, Rodrigo Noriega, Saahil Mehra, Alberto Salleo, Alessandro Martucci

Research output: Contribution to journalArticlepeer-review

80 Scopus citations

Abstract

We present a new colloidal synthesis of gallium-doped zinc oxide nanocrystals that are transparent in the visible and absorb in the near-infrared. Thermal decomposition of zinc stearate and gallium nitrate after hot injection of the precursors in a mixture of organic amines leads to nanocrystals with tunable properties according to gallium amount. Substitutional Ga3+ ions trigger a plasmonic resonance in the infrared region resulting from an increase in the free electrons concentration. These nanocrystals can be deposited by spin coating, drop casting, and spray coating resulting in homogeneous and high-quality thin films. The optical transmission of the Ga-ZnO nanoparticle assemblies in the visible is greater than 90%, and at the same time, the near-infrared absorption of the nanocrystals is maintained in the films as well. Several strategies to improve the films electrical and optical properties have been presented, such as UV treatments to remove the organic compounds responsible for the observed interparticle resistance and reducing atmosphere treatments on both colloidal solutions and thin films to increase the free carriers concentration, enhancing electrical conductivity and infrared absorption. The electrical resistance of the nanoparticle assemblies is about 30 kΩ/sq for the as-deposited, UV-exposed films, and it drops down to 300 Ω/sq after annealing in forming gas at 450 °C, comparable with state of the art tin-doped indium oxide coatings deposited from nanocrystal inks. © 2013 American Chemical Society.
Original languageEnglish (US)
Pages (from-to)3439-3448
Number of pages10
JournalJournal of the American Chemical Society
Volume135
Issue number9
DOIs
StatePublished - Feb 21 2013
Externally publishedYes

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