Ligand-Centered Reactivity of a Pseudo-Dearomatized Phosphorus-Nitrogen PN3P* Rhodium Complex towards Molecular Oxygen at Room Temperature

Kuo-Wei Huang; Chunhui Zhou; Kristin Munkerup; Yuan Wang; Pradip Das; Priyanka Chakraborty; Hanlin Hu; Changguang Yao; Mei-Hui Huang

doi:10.1039/c9qi01605h

Ligand-Centered Reactivity of a Pseudo-Dearomatized Phosphorus-Nitrogen PN3P* Rhodium Complex towards Molecular Oxygen at Room Temperature

Kuo-Wei Huang, Chunhui Zhou, Kristin Munkerup, Yuan Wang, Pradip Das, Priyanka Chakraborty, Hanlin Hu, Changguang Yao, Mei-Hui Huang

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The ligand of an organometallic complex is typically considered as a spectator which can be modified to tune the steric and electronic properties of the coordination environment. We herein demonstarted.

Original language	English (US)
Pages (from-to)	2017-2022
Number of pages	6
Journal	Inorganic Chemistry Frontiers
Volume	7
Issue number	10
DOIs	https://doi.org/10.1039/c9qi01605h
State	Published - Mar 20 2020

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10.1039/c9qi01605h

https://repository.kaust.edu.sa/bitstream/10754/662290/1/inorganic%20chemistry1.pdf

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title = "Ligand-Centered Reactivity of a Pseudo-Dearomatized Phosphorus-Nitrogen PN3P* Rhodium Complex towards Molecular Oxygen at Room Temperature",

abstract = "The ligand of an organometallic complex is typically considered as a spectator which can be modified to tune the steric and electronic properties of the coordination environment. We herein demonstarted.",

author = "Kuo-Wei Huang and Chunhui Zhou and Kristin Munkerup and Yuan Wang and Pradip Das and Priyanka Chakraborty and Hanlin Hu and Changguang Yao and Mei-Hui Huang",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the financial support from the King Abdullah University of Science and Technology (KAUST).",

year = "2020",

month = mar,

day = "20",

doi = "10.1039/c9qi01605h",

language = "English (US)",

volume = "7",

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journal = "Inorganic Chemistry Frontiers",

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publisher = "Royal Society of Chemistry",

number = "10",

}

Ligand-Centered Reactivity of a Pseudo-Dearomatized Phosphorus-Nitrogen PN3P* Rhodium Complex towards Molecular Oxygen at Room Temperature. / Huang, Kuo-Wei; Zhou, Chunhui; Munkerup, Kristin; Wang, Yuan; Das, Pradip; Chakraborty, Priyanka; Hu, Hanlin; Yao, Changguang; Huang, Mei-Hui.

In: Inorganic Chemistry Frontiers, Vol. 7, No. 10, 20.03.2020, p. 2017-2022.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Ligand-Centered Reactivity of a Pseudo-Dearomatized Phosphorus-Nitrogen PN3P* Rhodium Complex towards Molecular Oxygen at Room Temperature

AU - Huang, Kuo-Wei

AU - Zhou, Chunhui

AU - Munkerup, Kristin

AU - Wang, Yuan

AU - Das, Pradip

AU - Chakraborty, Priyanka

AU - Hu, Hanlin

AU - Yao, Changguang

AU - Huang, Mei-Hui

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the financial support from the King Abdullah University of Science and Technology (KAUST).

PY - 2020/3/20

Y1 - 2020/3/20

N2 - The ligand of an organometallic complex is typically considered as a spectator which can be modified to tune the steric and electronic properties of the coordination environment. We herein demonstarted.

AB - The ligand of an organometallic complex is typically considered as a spectator which can be modified to tune the steric and electronic properties of the coordination environment. We herein demonstarted.

UR - http://hdl.handle.net/10754/662290

UR - http://pubs.rsc.org/en/Content/ArticleLanding/2020/QI/C9QI01605H

UR - http://www.scopus.com/inward/record.url?scp=85086182770&partnerID=8YFLogxK

U2 - 10.1039/c9qi01605h

DO - 10.1039/c9qi01605h

M3 - Article

VL - 7

SP - 2017

EP - 2022

JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

SN - 2052-1545

IS - 10

ER -

Ligand-Centered Reactivity of a Pseudo-Dearomatized Phosphorus-Nitrogen PN3P* Rhodium Complex towards Molecular Oxygen at Room Temperature

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CCDC 1967061: Experimental Crystal Structure Determination : carbonyl-{N,N'-(3-oxopyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)]}-rhodium

CCDC 1967062: Experimental Crystal Structure Determination : carbonyl-{N,N'-(5-hydroperoxy-3-oxopyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)]}-rhodium

CCDC 1987739: Experimental Crystal Structure Determination : [mu-N,N',N'',N'''-(5,5'-dioxo[3,3'-bipyridinato]-2,2',6,6'(1H,1'H,5H,5'H)-tetraylidene)tetrakis[P,P-di-t-butyl(phosphinous amide)]]-dicarbonyl-di-rhodium

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Ligand-Centered Reactivity of a Pseudo-Dearomatized Phosphorus-Nitrogen PN3P* Rhodium Complex towards Molecular Oxygen at Room Temperature

Abstract

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Datasets

CCDC 1967061: Experimental Crystal Structure Determination : carbonyl-{N,N'-(3-oxopyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)]}-rhodium

CCDC 1967062: Experimental Crystal Structure Determination : carbonyl-{N,N'-(5-hydroperoxy-3-oxopyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)]}-rhodium

CCDC 1987739: Experimental Crystal Structure Determination : [mu-N,N',N'',N'''-(5,5'-dioxo[3,3'-bipyridinato]-2,2',6,6'(1H,1'H,5H,5'H)-tetraylidene)tetrakis[P,P-di-t-butyl(phosphinous amide)]]-dicarbonyl-di-rhodium

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