I.R. and E.X.A.F.S. characterisation of a supported osmium cluster carbonyl

Bernard Besson, B. Moraweck, A. K. Smith, J. M. Basset*, Rinaldo Psaro, A. Fusi, R. Ugo

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

72 Scopus citations

Abstract

Os3(CO)12 and Os3(CO)10(MeCN) 2 react with silanol groups of silica at 160 and 25°C, respectively, to give the grafted cluster Os3(CO)10(H) (OSi3 bonds on the leftside sign) (1) which has been characterized by i.r. spectroscopy, gas phase analysis, and E.X.A.F.S.; the model compound Os 3-(CO)10(H)(OSiPh3), obtained by the reaction of Os3-(CO)12 with Ph3SiOH, confirms the structure of the surface compound (1).

Original languageEnglish (US)
Pages (from-to)569-571
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number12
StatePublished - 1980
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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