Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.

Changguang Yao; Tonghuan Zhang; Chunhui Zhou; Kuo-Wei Huang

doi:10.1039/c9dt03003d

Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.

Changguang Yao, Tonghuan Zhang, Chunhui Zhou, Kuo-Wei Huang

Research output: Contribution to journal › Article › peer-review

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Abstract

H2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.

Original language	English (US)
Pages (from-to)	12817-12821
Number of pages	5
Journal	Dalton transactions (Cambridge, England : 2003)
Volume	48
Issue number	34
DOIs	https://doi.org/10.1039/c9dt03003d
State	Published - 2019

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10.1039/c9dt03003d

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title = "Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.",

abstract = "H2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.",

author = "Changguang Yao and Tonghuan Zhang and Chunhui Zhou and Kuo-Wei Huang",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the financial support from King Abdullah University of Science and Technology (KAUST).",

year = "2019",

doi = "10.1039/c9dt03003d",

language = "English (US)",

volume = "48",

pages = "12817--12821",

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publisher = "Royal Society of Chemistry",

number = "34",

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T1 - Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.

AU - Yao, Changguang

AU - Zhang, Tonghuan

AU - Zhou, Chunhui

AU - Huang, Kuo-Wei

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the financial support from King Abdullah University of Science and Technology (KAUST).

PY - 2019

Y1 - 2019

N2 - H2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.

AB - H2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.

UR - http://hdl.handle.net/10754/656479

UR - http://xlink.rsc.org/?DOI=C9DT03003D

UR - http://www.scopus.com/inward/record.url?scp=85071693588&partnerID=8YFLogxK

U2 - 10.1039/c9dt03003d

DO - 10.1039/c9dt03003d

M3 - Article

C2 - 31403641

VL - 48

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EP - 12821

JO - Dalton transactions (Cambridge, England : 2003)

JF - Dalton transactions (Cambridge, England : 2003)

SN - 1477-9226

IS - 34

ER -

Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.

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CCDC 1891954: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-{6-[(di-t-butylphosphanyl)amino]-3,3-diethylpyridin-2(3H)-ylidene}phosphinous amide)-hydrido-nickel trifluoromethanesulfonate

CCDC 1891947: Experimental Crystal Structure Determination : (N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-(trifluoromethanesulfonato)-nickel

CCDC 1891945: Experimental Crystal Structure Determination : (hydroxido[tris(pentafluorophenyl)]borate)-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-nickel

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Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.

Abstract

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Datasets

CCDC 1891954: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-{6-[(di-t-butylphosphanyl)amino]-3,3-diethylpyridin-2(3H)-ylidene}phosphinous amide)-hydrido-nickel trifluoromethanesulfonate

CCDC 1891947: Experimental Crystal Structure Determination : (N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-(trifluoromethanesulfonato)-nickel

CCDC 1891945: Experimental Crystal Structure Determination : (hydroxido[tris(pentafluorophenyl)]borate)-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-nickel

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