Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.

Changguang Yao; Tonghuan Zhang; Chunhui Zhou; Kuo-Wei Huang

doi:10.1039/c9dt03003d

Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.

Changguang Yao, Tonghuan Zhang, Chunhui Zhou, Kuo-Wei Huang

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

H2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.

Original language	English (US)
Pages (from-to)	12817-12821
Number of pages	5
Journal	Dalton transactions (Cambridge, England : 2003)
Volume	48
Issue number	34
DOIs	https://doi.org/10.1039/c9dt03003d
State	Published - 2019

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10.1039/c9dt03003d

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CCDC 1909960: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-{6-[(di-t-butylphosphanyl)amino]-3,5,5-trimethylpyridin-2(5H)-ylidene}phosphinous amide)-hydrido-nickel trifluoromethanesulfonate benzene solvate
Yao, C. (Creator), Zhang, T. (Creator), Zhou, C. (Creator), Huang, K. (Creator) & Zhang, T. (Creator), Cambridge Crystallographic Data Centre, Aug 16 2019
DOI: 10.5517/ccdc.csd.cc223gm9, http://hdl.handle.net/10754/664751
Dataset
CCDC 1891946: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-{6-[(di-t-butylphosphanyl)amino]-3,5,5-triethylpyridin-2(5H)-ylidene}phosphinous amide)-hydrido-nickel hydroxido[tris(pentafluorophenyl)]borate unknown solvate
Yao, C. (Creator), Zhang, T. (Creator), Zhou, C. (Creator), Huang, K. (Creator) & Zhang, T. (Creator), Cambridge Crystallographic Data Centre, Aug 17 2019
DOI: 10.5517/ccdc.csd.cc21hqjt, http://hdl.handle.net/10754/664749
Dataset
CCDC 1909961: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-{6-[(di-t-butylphosphanyl)amino]-3,5,5-tris(propan-2-yl)pyridin-2(5H)-ylidene}phosphinous amide)-hydrido-nickel trifluoromethanesulfonate
Yao, C. (Creator), Zhang, T. (Creator), Zhou, C. (Creator), Huang, K. (Creator) & Zhang, T. (Creator), Cambridge Crystallographic Data Centre, Aug 16 2019
DOI: 10.5517/ccdc.csd.cc223gnb, http://hdl.handle.net/10754/664750
Dataset

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@article{96d38f61879e4e288027dafa3f691200,

title = "Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.",

abstract = "H2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.",

author = "Changguang Yao and Tonghuan Zhang and Chunhui Zhou and Kuo-Wei Huang",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the financial support from King Abdullah University of Science and Technology (KAUST).",

year = "2019",

doi = "10.1039/c9dt03003d",

language = "English (US)",

volume = "48",

pages = "12817--12821",

journal = "Dalton transactions (Cambridge, England : 2003)",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "34",

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TY - JOUR

T1 - Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.

AU - Yao, Changguang

AU - Zhang, Tonghuan

AU - Zhou, Chunhui

AU - Huang, Kuo-Wei

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We acknowledge the financial support from King Abdullah University of Science and Technology (KAUST).

PY - 2019

Y1 - 2019

N2 - H2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.

AB - H2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.

UR - http://hdl.handle.net/10754/656479

UR - http://xlink.rsc.org/?DOI=C9DT03003D

UR - http://www.scopus.com/inward/record.url?scp=85071693588&partnerID=8YFLogxK

U2 - 10.1039/c9dt03003d

DO - 10.1039/c9dt03003d

M3 - Article

C2 - 31403641

VL - 48

SP - 12817

EP - 12821

JO - Dalton transactions (Cambridge, England : 2003)

JF - Dalton transactions (Cambridge, England : 2003)

SN - 1477-9226

IS - 34

ER -

Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.

Abstract

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CCDC 1909960: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-{6-[(di-t-butylphosphanyl)amino]-3,5,5-trimethylpyridin-2(5H)-ylidene}phosphinous amide)-hydrido-nickel trifluoromethanesulfonate benzene solvate

CCDC 1891946: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-{6-[(di-t-butylphosphanyl)amino]-3,5,5-triethylpyridin-2(5H)-ylidene}phosphinous amide)-hydrido-nickel hydroxido[tris(pentafluorophenyl)]borate unknown solvate

CCDC 1909961: Experimental Crystal Structure Determination : (P,P-di-t-butyl-N-{6-[(di-t-butylphosphanyl)amino]-3,5,5-tris(propan-2-yl)pyridin-2(5H)-ylidene}phosphinous amide)-hydrido-nickel trifluoromethanesulfonate

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