Interrogating the steric outcome during H2 heterolysis: in-plane steric effects in the regioselective protonation of the PN3P-pincer ligand.

Changguang Yao, Tonghuan Zhang, Chunhui Zhou, Kuo-Wei Huang

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

H2 heterolysis to generate well-defined nickel hydride-proton complexes was achieved by the 2nd generation PN3P-pincer nickel platform. The regioselective protonation in the ligand framework was demonstrated for the first time to highlight the importance of in-plane hindrance during the H2 splitting process.
Original languageEnglish (US)
Pages (from-to)12817-12821
Number of pages5
JournalDalton transactions (Cambridge, England : 2003)
Volume48
Issue number34
DOIs
StatePublished - 2019

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