Insights on Adsorption Characterization of Metal-Organic Frameworks: A Benchmark Study on the Novel soc-MOF

J. Moellmer, E. B. Celer, Ryan Luebke, Amy Cairns, R. Staudt*, Mohamed Eddaoudi, M. Thommes

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

126 Scopus citations

Abstract

In order to explore the potential of novel open metal organic frameworks (MOFs) with soc topology for gas storage applications, we performed a systematic physical adsorption study with Hydrogen, Methane and Carbon dioxide as adsorptives over a wide range of temperatures (77-323 K) and pressures (0-5 MPa) by using a volumetric low pressure adsorption analyzer equipped with a cryostat, and a high pressure gravimetric system. The advanced interpretation of our systematic adsorption data in combination with the results from a comprehensive structural and surface characterization allows one assessing the potential of these novel MOFs for gas storage and separation applications.

Original languageEnglish (US)
Pages (from-to)345-353
Number of pages9
JournalMicroporous and Mesoporous Materials
Volume129
Issue number3
DOIs
StatePublished - Apr 15 2010

Keywords

  • Adsorption
  • Characterization
  • Gas separation
  • High pressure
  • MOF

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials

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