In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks

Yi Liu, Melvin Jun Wei Tan, Fengxia Wei, Yufeng Tian, Tao Wu, Christian Kloc, Fengwei Huo, Qingyu Yan, Huey Hoon Hng, Jan Ma, Qichun Zhang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

Employing in situ-formed new organic ligands, two Pb(ii)-based metal-organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions indicate that the two compounds are semiconductors with band gaps of 1.70 and 1.78 eV. Magnetic properties reveal that they are temperature-independent diamagnetic.

Original languageEnglish (US)
Pages (from-to)75-78
Number of pages4
JournalCrystEngComm
Volume14
Issue number1
DOIs
StatePublished - Jan 7 2012

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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