Illuminating the nature and behavior of the active center: the key for photocatalytic H2 production in Co@NH2-MIL-125(Ti)

Ana Iglesias-Juez, Sonia Castellanos, Manuel Monte, Giovanni Agostini, Dmitrii Osadchii, Maxim A. Nasalevich, Jara G. Santaclara, Alma I. Olivos Suarez, Sergey L. Veber, Matvey V. Fedin, Jorge Gascon

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

Advanced atomically resolved characterization methods unveil the mechanism of a promising photocatalytic Co@MOF(Ti) system for H production. The combination of X-ray absorption spectroscopy (XAS) and electron paramagnetic resonance (EPR) experiments allows for the characterization of atomic and electronic rearrangements in the photoinduced species. This information provides the basis for the optimization of photocatalyst design.
Original languageEnglish (US)
Pages (from-to)17318-17322
Number of pages5
JournalJournal of Materials Chemistry A
Volume6
Issue number36
DOIs
StatePublished - 2018

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