Hydrotrifluoromethylthiolation of α-diazo esters-synthesis of α-SCF3 substituted esters

Quentin Lefebvre, Eleonora Fava, Pavlo Nikolaienko, Magnus Rueping*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

92 Scopus citations

Abstract

A practical protocol for hydrotrifluoromethylthiolation of diazo compounds has been developed. A range of diazo compounds in combination with a nucleophilic SCF3 source provided access to valuable trifluoromethylthiolated compounds. Furthermore, a methodology for the first double trifluoromethylthiolation was developed. This journal is

Original languageEnglish (US)
Pages (from-to)6617-6619
Number of pages3
JournalChemical Communications
Volume50
Issue number50
DOIs
StatePublished - Jun 25 2014

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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