Hydrothermal synthesis and characterization properties of C 7H 12N 2[H 2PO 4] 2.1/2H 2O

R. Elwej, N. Hannachi, K. Adil, F. Hlel*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

An orthophosphoric hybrid material was successfully prepared by a hydrothermal reaction at 110C. A single crystal X-ray structure, thermal behavior, IR, and NMR spectroscopy investigations are given for a new organic cation bis dihydrogenomonophosphate C 7H 12N 2[H 2PO 4] 2.1/2H 2O. The latter has been synthesized hydrothermally using 2,4-diaminotoluene (DAT) and orthophosphoric acid. The atomic arrangement can be described as inorganic sheets alternating with inorganic-organic layers. The organic group C 7H 12N + 2 is located between inorganic groups to build multiple hydrogen bonds to ensure the three-dimensional cohesion network. The thermal behavior and IR, NMR and impedance spectroscopy studies are discussed for the powder samples of this compound. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.

Original languageEnglish (US)
Pages (from-to)1173-1182
Number of pages10
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume187
Issue number10
DOIs
StatePublished - Oct 1 2012

Keywords

  • Hydrothermal synthesis
  • NMR, electrical properties
  • crystal structure
  • infrared spectroscopy

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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