Hydrosilylation of alkynes catalysed by platinum on titania

Francisco Alonso, Robison Buitrago, Yanina Moglie, Javier Ruiz-Martínez, Antonio Sepúlveda-Escribano, Miguel Yus

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48 Scopus citations

Abstract

The heterogeneous hydrosilylation of alkynes catalysed by platinum on titania is reported. A variety of hydrosilanes react with both terminal and internal alkynes to furnish the corresponding vinyl silanes in high yields and short reaction times as well as in a regio- and stereoselective manner. The catalyst can be easily recovered and reused in several consecutive cycles. © 2010 Elsevier B.V. All rights reserved.
Original languageEnglish (US)
JournalJournal of Organometallic Chemistry
Volume696
Issue number1
DOIs
StatePublished - Jan 1 2011
Externally publishedYes

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