Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes

Kuo Wei Huang, Robert M. Waymouth*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The η1-hydroxylamido half-titanocene complex, CpTi-Cl2(TEMPO) 1, hydrolyzes extremely efficiently to generate (CpTiClO)4 and the protonated hydroxylamine. The efficient hydrolysis chemistry provides selective syntheses of CpTi dialkoxide and diaryloxide complexes.

Original languageEnglish (US)
Pages (from-to)354-356
Number of pages3
JournalJournal of the Chemical Society. Dalton Transactions
Volume4
Issue number3
DOIs
StatePublished - Feb 7 2004
Externally publishedYes

ASJC Scopus subject areas

  • Inorganic Chemistry

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