[H4tren]3/2·(Al6F24)·3H2O, the most condensed fluoride in the Al(OH)3-tren-HFaq.-ethanol system

Karim Adil, J. Marrot, M. Leblanc, V. Maisonneuve*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

The most condensed crystalline fluoride that appears in the Al(OH)3-tren-HFaq.-ethanol system at 190 °C is found to be [H4tren]3/2·(Al6F24)·3H2O. The structure is monoclinic, P21/c, with a = 21.939(1) Å, b = 6.7180(2) Å, c = 23.329(1) Å, β = 111.324(2)°. (Al6F24) chains result from the connection of (Al7F30)9- polyanions by opposite AlF6 octahedra. Hydrogen bonds are established between the (Al6F24) chains and ordered or disordered [H4tren]4+ cations and water molecules.

Original languageEnglish (US)
Pages (from-to)531-534
Number of pages4
JournalSolid State Sciences
Volume9
Issue number6
DOIs
StatePublished - Jan 1 2007

Keywords

  • Fluoride
  • Tris-2-(aminoethyl)amine
  • X-ray diffraction

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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