Homogeneous catalysis in water Part II. Synthesis and characterization of ruthenium water-soluble complexes

E. Fache, C. Santini, F. Senocq, J. M. Basset*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

58 Scopus citations

Abstract

Seven water-soluble complexes of ruthenium and TPPTS have been prepared and characterized (TPPTS is the trisodium salt of the tri(m-sulfophenyl)phosphine):[RuCl2(TPPTS)2]2 1, RuHCl(TPPTS)3 2, RuH(OAc)(TPPS)3 3, RuH2(TPPTS)4 4, RuHI(TPPTS)3 5, RuCl2(CO)2(TPPTS)2 6 and [Ru(OAc)(CO)2(TPPTS)]2 7. Spectroscopic investigations have shown that in solution they have the same structures as their organosoluble analogues containing the ligand PPh3.

Original languageEnglish (US)
Pages (from-to)331-336
Number of pages6
JournalJournal of Molecular Catalysis
Volume72
Issue number3
DOIs
StatePublished - Mar 15 1992
Externally publishedYes

ASJC Scopus subject areas

  • Engineering(all)

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