Highly twisted 1,2:8,9-dibenzozethrenes: Synthesis, ground state, and physical properties

Zhe Sun, Bin Zheng, Pan Hu, Kuo-Wei Huang, Jishan Wu

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Two soluble and stable 1,2:8,9-dibenzozethrene derivatives (3a,b) are synthesized through a palladium-catalyzed cyclodimerization reaction. X-ray crystallographic analysis shows that these molecules are highly twisted owing to congestion at the cove region. Broken-symmetry DFT calculations predict that they have a singlet biradical ground state with a smaller biradical character and a large singlet-triplet energy gap; these predictions are supported by NMR and electronic absorption measurements. They have small energy gaps and exhibit farred/near-infrared absorption/emission and amphoteric redox behaviors.
Original languageEnglish (US)
Pages (from-to)1549-1553
Number of pages5
JournalChemPlusChem
Volume79
Issue number11
DOIs
StatePublished - Aug 8 2014

ASJC Scopus subject areas

  • Chemistry(all)

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