High performance anode-supported intermediate temperature solid oxide fuel cells (IT-SOFCs) with La0.8Sr0.2Ga0.8Mg0.2O3-δ electrolyte films prepared by electrophoretic deposition

Francesco Bozza*, Riccardo Polini, Enrico Traversa

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

67 Scopus citations

Abstract

Remarkable power density was obtained for anode-supported solid oxide fuel cells (SOFCs) based on La0.8Sr0.2Ga0.8Mg0.2O3-δ (LSGM) electrolyte films, fabricated following an original procedure that allowed avoiding undesired reactions between LSGM and electrode materials, especially Ni. Electrophoretic deposition (EPD) was used for the fabrication of 30 μm-thick electrolyte films. Anode supports were made of La0.4Ce0.6O2-x (LDC). The LSGM powder was deposited by EPD on an LDC green tape-cast membrane added with carbon powder, both as pore former and substrate conductivity booster. A subsequent co-firing step at 1490 °C produced dense electrolyte films on porous LDC skeletons. Then, a La0.8Sr0.2Fe0.8Co0.2O3-δ (LSFC) cathode was applied by slurry-coating and calcined at 1100 °C. Finally, the porous LDC layer was impregnated with molten Ni nitrate to obtain, after calcination at 900 °C, a composite NiO-LDC anode. Maximum power densities of 780, 450, 275, 175, and 100 mW/cm2 at 700, 650, 600, 550, and 500 °C, respectively, were obtained using H2 as fuel and air as oxidant, demonstrating the success of the processing strategy. As a comparison, electrolyte-supported SOFCs made of the same materials were tested, showing a maximum power density of 150 mW/cm2 at 700 °C, more than 5 times smaller than the anode-supported counterpart.

Original languageEnglish (US)
Pages (from-to)1680-1683
Number of pages4
JournalElectrochemistry Communications
Volume11
Issue number8
DOIs
StatePublished - Aug 1 2009

Keywords

  • Anode-supported
  • Electrolyte
  • Electrophoretic deposition (EPD)
  • LSGM
  • Solid oxide fuel cell (SOFC)
  • Thick films

ASJC Scopus subject areas

  • Electrochemistry

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