The title compound, [Ca3(C13H25N2O)6]·C6H14, is a trinuclear complex with all Ca atoms presenting octa-hedral coordination. The central Ca atom (as well as the hexane solvent mol-ecule) is located on a crystallographic twofold rotation axis and is coordinated by six bridging O atoms, with Ca - O distances ranging from 2.344 (1) to 2.351 (1) Å. The terminal Ca atoms are coordinated by three bridging O atoms, with Ca - O distances ranging from 2.311 (1) to 2.335 (1) Å, and three N atoms of the Β-ketoiminate ligands, with Ca - N distances ranging from 2.432 (1) to 2.452 (1) Å. One of the diisopropylamino groups is disordered over two positions, with site occipancy factors of ca 0.54 and 0.46.
|Original language||English (US)|
|Journal||Acta Crystallographica Section E: Structure Reports Online|
|State||Published - Jul 31 2007|
ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics