From synthesis to chemical reactivity of supported d0 complexes. Part 2. Reactivity of silica-anchored alkylzirconium complexes. An attempt toward functionaltzation of alkanes

Françoise Quignard*, Agnès Choplin, Jean-Marie Maurice Basset

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

Silica-anchored alkyl zirconium complexes [Zr]s-R (R = cyclooctyl, Pr or Me) have been generated by reaction of [Zr]s-H complexes with the relevant alkanes. Their stoichiometric reactivity towards molecules such as carbon monoxide and olefins was studied in order to estimate the potential of such systems to activate and functionalize alkanes catalytically.

Original languageEnglish (US)
Pages (from-to)2411-2414
Number of pages4
JournalJournal of the Chemical Society, Dalton Transactions
Issue number16
DOIs
StatePublished - Dec 1 1994

ASJC Scopus subject areas

  • Chemistry(all)

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