Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air

Mohammed Tchalala; Prashant Bhatt; Karumbaiah Chappanda Nanaiah; S R Tavares; Karim Adil; Youssef Belmabkhout; Aleksander Shkurenko; Amandine Cadiau; N Heymans; G De Weireld; G Maurin; Khaled N. Salama; Mohamed Eddaoudi

doi:10.1038/s41467-019-09157-2

Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air

Mohammed Tchalala, Prashant Bhatt, Karumbaiah Chappanda Nanaiah, S R Tavares, Karim Adil, Youssef Belmabkhout, Aleksander Shkurenko, Amandine Cadiau, N Heymans, G De Weireld, G Maurin, Khaled N. Salama, Mohamed Eddaoudi

Research output: Contribution to journal › Article › peer-review

87 Scopus citations

Abstract

Conventional SO2 scrubbing agents, namely calcium oxide and zeolites, are often used to remove SO2 using a strong or irreversible adsorption-based process. However, adsorbents capable of sensing and selectively capturing this toxic molecule in a reversible manner, with in-depth understanding of structure-property relationships, have been rarely explored. Here we report the selective removal and sensing of SO2 using recently unveiled fluorinated metal-organic frameworks (MOFs). Mixed gas adsorption experiments were performed at low concentrations ranging from 250 p.p.m. to 7% of SO2. Direct mixed gas column breakthrough and/or column desorption experiments revealed an unprecedented SO2 affinity for KAUST-7 (NbOFFIVE-1-Ni) and KAUST-8 (AlFFIVE-1-Ni) MOFs. Furthermore, MOF-coated quartz crystal microbalance transducers were used to develop sensors with the ability to detect SO2 at low concentrations ranging from 25 to 500 p.p.m.

Original language	English (US)
Journal	Nature Communications
Volume	10
Issue number	1
DOIs	https://doi.org/10.1038/s41467-019-09157-2
State	Published - Mar 22 2019

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CCDC 1871683: Experimental Crystal Structure Determination : catena-[(mu-fluoro)-(mu-oxo)-bis(mu-pyrazine)-tetrafluoro-nickel(ii)-niobium(v) (sulfur dioxide)]
Tavares, S. R. (Creator), Adil, K. (Creator), Belmabkhout, Y. (Creator), Shkurenko, A. (Creator), Cadiau, A. (Creator), Heymans, N. (Creator), De Weireld, G. (Creator), Maurin, G. (Creator), Salama, K. (Creator), Eddaoudi, M. (Creator), Tchalala, M. (Creator), Bhatt, P. (Creator), Nanaiah, K. C. (Creator), Tavares, S. R. (Creator), Heymans, N. (Creator), De Weireld, G. (Creator), Maurin, G. (Creator) & Tchalala, M. (Creator), Cambridge Crystallographic Data Centre, 2019
DOI: 10.5517/ccdc.csd.cc20tmwc, http://hdl.handle.net/10754/664799
Dataset
CCDC 1871684: Experimental Crystal Structure Determination : catena-[bis(mu-fluoro)-bis(mu-pyrazine)-trifluoro-aluminium(iii)-nickel(ii) (sulfur dioxide)]
Tavares, S. R. (Creator), Adil, K. (Creator), Belmabkhout, Y. (Creator), Shkurenko, A. (Creator), Cadiau, A. (Creator), Heymans, N. (Creator), De Weireld, G. (Creator), Maurin, G. (Creator), Salama, K. (Creator), Eddaoudi, M. (Creator), Tchalala, M. (Creator), Bhatt, P. (Creator), Nanaiah, K. C. (Creator), Tavares, S. R. (Creator), Heymans, N. (Creator), De Weireld, G. (Creator), Maurin, G. (Creator) & Tchalala, M. (Creator), Cambridge Crystallographic Data Centre, 2019
DOI: 10.5517/ccdc.csd.cc20tmxd, http://hdl.handle.net/10754/664740
Dataset

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Tchalala, Mohammed ; Bhatt, Prashant ; Nanaiah, Karumbaiah Chappanda ; Tavares, S R ; Adil, Karim ; Belmabkhout, Youssef ; Shkurenko, Aleksander ; Cadiau, Amandine ; Heymans, N ; De Weireld, G ; Maurin, G ; Salama, Khaled N. ; Eddaoudi, Mohamed. / Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air. In: Nature Communications. 2019 ; Vol. 10, No. 1.

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title = "Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air",

abstract = "Conventional SO2 scrubbing agents, namely calcium oxide and zeolites, are often used to remove SO2 using a strong or irreversible adsorption-based process. However, adsorbents capable of sensing and selectively capturing this toxic molecule in a reversible manner, with in-depth understanding of structure-property relationships, have been rarely explored. Here we report the selective removal and sensing of SO2 using recently unveiled fluorinated metal-organic frameworks (MOFs). Mixed gas adsorption experiments were performed at low concentrations ranging from 250 p.p.m. to 7% of SO2. Direct mixed gas column breakthrough and/or column desorption experiments revealed an unprecedented SO2 affinity for KAUST-7 (NbOFFIVE-1-Ni) and KAUST-8 (AlFFIVE-1-Ni) MOFs. Furthermore, MOF-coated quartz crystal microbalance transducers were used to develop sensors with the ability to detect SO2 at low concentrations ranging from 25 to 500 p.p.m.",

author = "Mohammed Tchalala and Prashant Bhatt and Nanaiah, {Karumbaiah Chappanda} and Tavares, {S R} and Karim Adil and Youssef Belmabkhout and Aleksander Shkurenko and Amandine Cadiau and N Heymans and {De Weireld}, G and G Maurin and Salama, {Khaled N.} and Mohamed Eddaoudi",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CCF/1/1972–25–01, CCF/1/1972–27–01, OSR-2017-CPF-3325 Acknowledgements: Research reported in this publication was supported by KAUST funds and KAUST funding grants (CCF/1/1972–25–01, CCF/1/1972–27–01, and OSR-2017-CPF-3325)",

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doi = "10.1038/s41467-019-09157-2",

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Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air. / Tchalala, Mohammed; Bhatt, Prashant; Nanaiah, Karumbaiah Chappanda; Tavares, S R; Adil, Karim; Belmabkhout, Youssef; Shkurenko, Aleksander; Cadiau, Amandine; Heymans, N; De Weireld, G; Maurin, G; Salama, Khaled N.; Eddaoudi, Mohamed.

In: Nature Communications, Vol. 10, No. 1, 22.03.2019.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air

AU - Tchalala, Mohammed

AU - Bhatt, Prashant

AU - Nanaiah, Karumbaiah Chappanda

AU - Tavares, S R

AU - Adil, Karim

AU - Belmabkhout, Youssef

AU - Shkurenko, Aleksander

AU - Cadiau, Amandine

AU - Heymans, N

AU - De Weireld, G

AU - Maurin, G

AU - Salama, Khaled N.

AU - Eddaoudi, Mohamed

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): CCF/1/1972–25–01, CCF/1/1972–27–01, OSR-2017-CPF-3325 Acknowledgements: Research reported in this publication was supported by KAUST funds and KAUST funding grants (CCF/1/1972–25–01, CCF/1/1972–27–01, and OSR-2017-CPF-3325)

PY - 2019/3/22

Y1 - 2019/3/22

N2 - Conventional SO2 scrubbing agents, namely calcium oxide and zeolites, are often used to remove SO2 using a strong or irreversible adsorption-based process. However, adsorbents capable of sensing and selectively capturing this toxic molecule in a reversible manner, with in-depth understanding of structure-property relationships, have been rarely explored. Here we report the selective removal and sensing of SO2 using recently unveiled fluorinated metal-organic frameworks (MOFs). Mixed gas adsorption experiments were performed at low concentrations ranging from 250 p.p.m. to 7% of SO2. Direct mixed gas column breakthrough and/or column desorption experiments revealed an unprecedented SO2 affinity for KAUST-7 (NbOFFIVE-1-Ni) and KAUST-8 (AlFFIVE-1-Ni) MOFs. Furthermore, MOF-coated quartz crystal microbalance transducers were used to develop sensors with the ability to detect SO2 at low concentrations ranging from 25 to 500 p.p.m.

AB - Conventional SO2 scrubbing agents, namely calcium oxide and zeolites, are often used to remove SO2 using a strong or irreversible adsorption-based process. However, adsorbents capable of sensing and selectively capturing this toxic molecule in a reversible manner, with in-depth understanding of structure-property relationships, have been rarely explored. Here we report the selective removal and sensing of SO2 using recently unveiled fluorinated metal-organic frameworks (MOFs). Mixed gas adsorption experiments were performed at low concentrations ranging from 250 p.p.m. to 7% of SO2. Direct mixed gas column breakthrough and/or column desorption experiments revealed an unprecedented SO2 affinity for KAUST-7 (NbOFFIVE-1-Ni) and KAUST-8 (AlFFIVE-1-Ni) MOFs. Furthermore, MOF-coated quartz crystal microbalance transducers were used to develop sensors with the ability to detect SO2 at low concentrations ranging from 25 to 500 p.p.m.

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U2 - 10.1038/s41467-019-09157-2

DO - 10.1038/s41467-019-09157-2

M3 - Article

C2 - 30902992

VL - 10

JO - Nature Communications

JF - Nature Communications

SN - 2041-1723

IS - 1

ER -

Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air

Abstract

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CCDC 1871683: Experimental Crystal Structure Determination : catena-[(mu-fluoro)-(mu-oxo)-bis(mu-pyrazine)-tetrafluoro-nickel(ii)-niobium(v) (sulfur dioxide)]

CCDC 1871684: Experimental Crystal Structure Determination : catena-[bis(mu-fluoro)-bis(mu-pyrazine)-trifluoro-aluminium(iii)-nickel(ii) (sulfur dioxide)]

Cite this