TY - JOUR
T1 - Facial One-Pot Synthesis of D 3h Symmetric Bicyclocalix[2]arene[2]triazines and Their Layered Comb Self-Assembly
AU - Chen, Yin
AU - Jiahui, Wang
AU - Xu, Hai
AU - Qianqian, Li
AU - Jing, Jiang
N1 - KAUST Repository Item: Exported on 2020-10-01
PY - 2017/11/23
Y1 - 2017/11/23
N2 - A number of D3h symmetric bicyclocalix[2]arene[2]triazine core compounds were synthesized via a general and good-yielding (43-48% yield) facile protocol starting from cyanuric halides, phloroglucinol and K2CO3 under very mild reaction conditions. These cage-like compounds are tolerate with different reaction conditions and can be derived with other functional groups in high yield. The X-ray crystal structures show these compounds have slightly distorted D3h symmetric structures. Due to the unique molecular topological structure, bicyclocalix[2]arene[2]triazine molecules form unique layered comb networks when hydrogen bond groups exist (such as CO2H, B(OH)2), which represent a new kind of building block unit for supramolecular architectures.
AB - A number of D3h symmetric bicyclocalix[2]arene[2]triazine core compounds were synthesized via a general and good-yielding (43-48% yield) facile protocol starting from cyanuric halides, phloroglucinol and K2CO3 under very mild reaction conditions. These cage-like compounds are tolerate with different reaction conditions and can be derived with other functional groups in high yield. The X-ray crystal structures show these compounds have slightly distorted D3h symmetric structures. Due to the unique molecular topological structure, bicyclocalix[2]arene[2]triazine molecules form unique layered comb networks when hydrogen bond groups exist (such as CO2H, B(OH)2), which represent a new kind of building block unit for supramolecular architectures.
UR - http://hdl.handle.net/10754/626234
UR - http://www.sciencedirect.com/science/article/pii/S1319610317301370
UR - http://www.scopus.com/inward/record.url?scp=85035210697&partnerID=8YFLogxK
U2 - 10.1016/j.jscs.2017.11.003
DO - 10.1016/j.jscs.2017.11.003
M3 - Article
VL - 22
SP - 628
EP - 635
JO - Journal of Saudi Chemical Society
JF - Journal of Saudi Chemical Society
SN - 1319-6103
IS - 5
ER -