Extending the Second-Generation Phosphorus-Nitrogen PN3
-Pincer Ligand Family through Ligand Post-Modification

Mei-Hui Huang; Jinsong Hu; Kuo-Wei Huang

doi:10.1002/jccs.201700205

Extending the Second-Generation Phosphorus-Nitrogen PN3 -Pincer Ligand Family through Ligand Post-Modification

Mei-Hui Huang, Jinsong Hu, Kuo-Wei Huang

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.

Original language	English (US)
Pages (from-to)	60-64
Number of pages	5
Journal	Journal of the Chinese Chemical Society
Volume	65
Issue number	1
DOIs	https://doi.org/10.1002/jccs.201700205
State	Published - Oct 2 2017

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title = "Extending the Second-Generation Phosphorus-Nitrogen PN3 -Pincer Ligand Family through Ligand Post-Modification",

abstract = "A series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.",

author = "Mei-Hui Huang and Jinsong Hu and Kuo-Wei Huang",

note = "KAUST Repository Item: Exported on 2021-02-11 Acknowledged KAUST grant number(s): URF/1/3018–01-01 Acknowledgements: Financial support for this work was provided by the King Abdullah University of Science and Technology (URF/1/3018–01-01).",

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doi = "10.1002/jccs.201700205",

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AU - Huang, Mei-Hui

AU - Hu, Jinsong

AU - Huang, Kuo-Wei

N1 - KAUST Repository Item: Exported on 2021-02-11 Acknowledged KAUST grant number(s): URF/1/3018–01-01 Acknowledgements: Financial support for this work was provided by the King Abdullah University of Science and Technology (URF/1/3018–01-01).

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N2 - A series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.

AB - A series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.

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Extending the Second-Generation Phosphorus-Nitrogen PN3 -Pincer Ligand Family through Ligand Post-Modification

Abstract

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