Abstract
A series of air-stable nickel complexes containing triazine-based PN3P-pincer ligands were synthesized and fully characterized. Complex 3 contains a de-aromatized central triazine ring from the deprotonation of one of the N–H arms. With a post-modification strategy, the Me-PN3P*NiCl complex (3) could be converted into a new class of diimine–traizine PN3P-pincer nickel complexes.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 60-64 |
| Number of pages | 5 |
| Journal | Journal of the Chinese Chemical Society |
| Volume | 65 |
| Issue number | 1 |
| DOIs | |
| State | Published - Oct 2 2017 |
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Datasets
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CCDC 1866914: Experimental Crystal Structure Determination : (N,N'-(1-ethyl-6-methyl-1,3,5-triazine-2,4(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-iodo-nickel
Huang, M. (Creator), Hu, J. (Creator) & Huang, K. (Creator), Cambridge Crystallographic Data Centre, Oct 13 2018
DOI: 10.5517/ccdc.csd.cc20np1f, http://hdl.handle.net/10754/663888
Dataset
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CCDC 1866913: Experimental Crystal Structure Determination : chloro-(N,N'-(1-ethyl-6-methyl-1,3,5-triazine-2,4(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-nickel
Huang, M. (Creator), Hu, J. (Creator) & Huang, K. (Creator), Cambridge Crystallographic Data Centre, Oct 13 2018
DOI: 10.5517/ccdc.csd.cc20np0d, http://hdl.handle.net/10754/663889
Dataset
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CCDC 1866912: Experimental Crystal Structure Determination : chloro-(P,P-di-t-butyl-N-{6-[(di-t-butylphosphanyl)amino]-4-methyl-1,3,5-triazin-2(1H)-ylidene}phosphinous amidato)-nickel chloroform solvate
Huang, M. (Creator), Hu, J. (Creator) & Huang, K. (Creator), Cambridge Crystallographic Data Centre, Oct 13 2018
DOI: 10.5517/ccdc.csd.cc20nnzb, http://hdl.handle.net/10754/663890
Dataset