Extending the coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) to cobalt centers: First examples of Co-PTA complexes and of a metal complex with the PTA oxide ligand

Łukasz Jaremko, Alexander M. Kirillov, Piotr Smoleński, Tadeusz Lis, Armando J.L. Pombeiro

Research output: Contribution to journalArticlepeer-review

43 Scopus citations

Abstract

Water-soluble CoIII and CoII complexes with P- or N-coordinated PTA or PTA oxide ligands, respectively, have been prepared and fully characterized, constituting the first examples of cobalt compounds bearing PTA or any ligand with a cage-like PTA core, the latter complex providing also the first PTA oxide coordination to a metal center.

Original languageEnglish (US)
Pages (from-to)2922-2924
Number of pages3
JournalInorganic Chemistry
Volume47
Issue number8
DOIs
StatePublished - Apr 21 2008
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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