Experimental determination of bulk modulus of 14Å tobermorite using high pressure synchrotron X-ray diffraction

Jae Eun Oh, Simon M. Clark, Hans-Rudolf Wenk, Paulo J. M. Monteiro

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Abstract

Using a diamond anvil cell, 14 Å tobermorite, a structural analogue of calcium silicate hydrates (C-S-H), was examined by high-pressure synchrotron X-ray diffraction up to 4.8 GPa under hydrostatic conditions. The bulk modulus of 14 Å tobermorite was calculated, K o = 47 GPa. Comparison of the current results with previous high pressure studies on C-S-H(I) indicates that: (1) the compression behavior of the lattice parameters a and b of 14 Å tobermorite and C-S-H(I) are very similar, implying that both materials may have very similar Ca-O layers, and also implying that an introduction of structural defects into the Ca-O layers may not substantially change in-plane incompressibility of the ab plane of 14 Å tobermorite; and (2) the bulk modulus values of 14 Å tobermorite and C-S-H(I) are dominated by the incompressibility of the lattice parameter c, which is directly related to the interlayer spacing composed of dreierketten silicate chains, interlayer Ca, and water molecules. © 2011 Elsevier Ltd. All rights reserved.
Original languageEnglish (US)
Pages (from-to)397-403
Number of pages7
JournalCement and Concrete Research
Volume42
Issue number2
DOIs
StatePublished - Feb 2012
Externally publishedYes

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