Ethanol and water adsorption in methanol-derived ZIF-71

Ryan P. Lively, Michelle E. Dose, Joshua A. Thompson, Benjamin A. McCool, Ronald R. Chance, William J. Koros

Research output: Contribution to journalArticlepeer-review

80 Scopus citations

Abstract

A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions. © The Royal Society of Chemistry 2011.
Original languageEnglish (US)
Pages (from-to)8667
JournalChemical Communications
Volume47
Issue number30
DOIs
StatePublished - 2011
Externally publishedYes

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